(Benzoylacetonato-κ2 O,O′)dicarbonylrhodium(I)
نویسندگان
چکیده
In the title compound, [Rh(C10H9O2)(CO)2], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0.017 Å. In the crystal, C-H⋯O inter-action is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic inter-actions [3.308 (3) and 3.461 (3) Å] between neighbouring Rh(I) atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction.
منابع مشابه
Azido(benzoylacetonato-κ2 O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ3 N,N′,O]cobalt(III)
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