(Benzoyl­acetonato-κ2 O,O′)dicarbonyl­rhodium(I)

نویسندگان

  • Carla Pretorius
  • Andreas Roodt
چکیده

In the title compound, [Rh(C10H9O2)(CO)2], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0.017 Å. In the crystal, C-H⋯O inter-action is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic inter-actions [3.308 (3) and 3.461 (3) Å] between neighbouring Rh(I) atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012